In order for the pie to take the whole width/height of the container you will need to:
1) Disable callouts / labels;
2) Set all margins to zero;
3) Disable slice pullout functionality.
Like this:
chart.labelsEnabled = false; chart.autoMargins = false; chart.marginTop = 0; chart.marginBottom = 0; chart.marginLeft = 0; chart.marginRight = 0; chart.pullOutRadius = 0;
Or if you are using JSON config:
AmCharts.makeChart("chartdiv", {
...
labelsEnabled: false,
autoMargins: false,
marginTop: 0,
marginBottom: 0,
marginLeft: 0,
marginRight: 0,
pullOutRadius: 0,
...
});